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    • 专利摘要:
    HARDNESS STEEL ARTICLE AND METHOD OF MAKING A double hardness steel article comprises a first air-hardenable steel alloy having a first metallurgically hardness attached to a second air-hardenable steel alloy having a second hardness. A method of manufacturing a hard steel article comprises providing a first air-curable steel alloy part comprising a first matching surface and having a first part hardness and providing a second air-curable steel alloy part comprising a second matching surface and having a second part hardness. The first piece of air-curable steel alloy is metallurgically attached to the second piece of air-curable steel alloy to form a metallurgically attached assembly, and the metallurgically attached assembly is hot rolled to provide a metallurgical bond between the first matching surface and the second correspondence surface.
    公开号:BR112013017287B1
    申请号:R112013017287-8
    申请日:2011-12-22
    公开日:2020-06-23
    发明作者:Njall Stefansson；Ronald E. Bailey；Glenn J. Swiatek
    申请人:Ati Properties Llc；
    IPC主号:
    专利说明:

    TECHNOLOGY FIELD
    The present disclosure is directed to the fields of double hardness steels and methods of making double hardness steels. DESCRIPTION OF THE TECHNOLOGY BACKGROUND
    Double-bonded steel reinforcement by laminating is a highly effective reinforcement material. An example of this type of steel armor is the ATI K12®-MIL Dual Hard armor plate which is available from ATI Defense, Washington, PA, USA. The ATI K12®-MIL Dual Hard armor is disclosed as a modality in US patent 5,749,140 which is incorporated herein by reference in its entirety. The ATI K12®-MIL Dual Hard armor plate is a laminated material having a high hardness front side and a softer back side. In use, the hard front side of the armor breaks and flattens the incoming projectile and the back side captures and still absorbs the energy from the deformed projectile.
    Although the double hardened steel reinforcement connected by conventional rolling has resistance to substantial ballistic penetration, it is difficult and expensive to produce the material. Post-bonding heat treatments by complex rolling and other processing are necessary to achieve the desired mechanical and ballistic properties in double-bonded steel reinforcement by conventional rolling. In particular, it is necessary to austenitize, temper in oil and temper the material after lamination. In addition, these process steps can only be performed on a small section of a plate connected by lamination at a time, because excessive warping of the plate, otherwise, may occur due to differences in the coefficients of thermal expansion and the transformation temperatures of the two alloys connected by lamination.
    In addition, after heat treatment, conventional double-strength steel reinforcement plates must undergo a complex flattening treatment. Only a limited number of manufacturing sites are adequately equipped to perform the flattening treatment. Also, the need to carry out flattening treatment on slabs effectively limits the size of double hardness steel armor plates bonded by conventional magnetization to sizes no larger than about 20 x 20 inches (50.8 x 50.8 cm) ). Larger plates must be manufactured by joining multiple smaller plates, substantially increasing the cost of the part and the time of manufacture, as well as potentially negatively affecting the integrity of the part.
    Consequently, there is a need for a method of fabricating double hardened steel armor bonded by Ionization that does not require conventional post-linkage steps, such as austenitization and oil quenching, and / or that reduces the need for complex tempering and flattening for many applications. More generally, there is a need for an improved method of making double-strength steel armor. SUMMARY
    According to a non-limiting aspect of the present disclosure, a double-hardened steel article comprises a first air-hardenable steel alloy having a first alloy hardness and a second self-correcting and air-curable steel alloy having a second alloy hardness . In certain embodiments, the first alloy hardness is greater than the second alloy hardness. A metallurgical bonding region exists between the first air-curable steel alloy and the second air-curable steel alloy.
    According to another non-limiting aspect of the present disclosure, a double-hardened steel armature comprises a first air-hardenable steel alloy having a first alloy hardness of at least 574 BHN and a second air-hardenable steel alloy having a second alloy hardness in a range of 477 BHN to 534 BHN, inclusive. The first air-curable steel alloy comprises, in weight percent, 0.42 to 0.52 carbon, 3.75 to 4.25 nickel, 1.00 to 1.50 chromium, 0.22 to 0 , 37 molybdenum, 0.20 to 1.00 manganese, 0.20 to 0.50 silicon, up to 0.020 phosphorus, up to 0.005 sulfur, iron and impurities. The second air-curable steel alloy comprises, in weight percent, 0.22 to 0.32 carbon, 3.50 to 4.00 nickel, 1.60 to 2.00 chromium, 0.22 to 0, 37 molybdenum, 0.80 to 1.20 manganese, 0.25 to 0.45 silicon, up to 0.020 phosphorus, up to 0.005 sulfur, iron and impurities. The metallurgical connection region exists between the first air-curable steel alloy and the second air-curable and self-correcting steel alloy.
    In accordance with yet another aspect of the present disclosure, a method of making a double-hardened steel armature comprises: providing a first piece of air-curable steel alloy comprising a first matching surface and having a first piece hardness; and providing a second piece of air-curable steel alloy comprising a second matching surface and having a second piece hardness. The first part hardness is greater than the second part hardness. The first part hardness and the second part hardness are arranged so that at least a portion of the first correspondence surface contacts at least a portion of the second correspondence surface, and the first part and the second part are metallurgically fixed to form a metallurgically fixed assembly. The metallurgically fixed assembly is hot rolled to provide a metallurgical bond between the first matching surface and the second matching surface. BRIEF DESCRIPTION OF THE DRAWINGS
    A Figura 1A é uma vista esquemática em perspectiva de uma modalidade não limitativa do artigo de aço de dureza dupla de acordo com a presente divulga ção; A Figura 1B é uma vista esquemática em corte transversal do artigo de aço de dupla dureza da modalidade mostrada naFigura 1A; e A Figura 2 é um fluxograma de uma modalidade não limitativa de um método de fabricação de um artigo de aço de dupla dureza de acordo com a presente divulgação. The characteristics and advantages of the methods described here can be better understood by reference to the accompanying drawings, in which: Figure 1A is a schematic perspective view of a non-limiting embodiment of the double hardness steel article according to the present disclosure; Figure 1B is a schematic cross-sectional view of the double hardness steel article of the embodiment shown in Figure 1A; and Figure 2 is a flowchart of a non-limiting modality of a method of manufacturing a double hardness steel article according to the present disclosure.

    The reader will appreciate the preceding information, as well as others, when considering the following detailed description of certain non-limiting modalities in accordance with the present disclosure. DETAILED DESCRIPTION OF CERTAIN NON-LIMITATIVE MODALITIES
    It should be understood that certain descriptions of the modalities disclosed herein have been simplified to illustrate only those elements, characteristics and aspects that are relevant to a clear understanding of the disclosed modalities, while eliminating, for purposes of clarity, other elements, characteristics and aspects. Persons of ordinary skill in the art, after examining the present description of the disclosed modalities, will recognize that other elements and / or characteristics may be desirable in a particular application or application of the disclosed modalities. However, as these other elements and / or characteristics can be readily determined and applied by persons of ordinary skill in the art by examining the present description of the disclosed modalities and, therefore, are not necessary for a complete understanding of the disclosed modalities, a description of such elements and / or resources are not provided here. As such, it is to be understood that the description here provided is merely exemplary and illustrative of the disclosed modalities and is not intended to limit the scope of the invention as defined only by the claims.
    In the present description of non-limiting modalities, except in the examples of operation or where otherwise indicated, all numbers expressing quantities or characteristics are to be understood as being modified in all cases by the term "about". Therefore, unless otherwise indicated, all numerical parameters set out in the following description are approximations that may vary depending on the desired properties that are sought in the material in accordance with the present disclosure. At a minimum, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be interpreted in light of the number of significant digits reported and by the application of common rounding techniques.
    In addition, any numerical range recited here is intended to include all sub-ranges encompassed in it. For example, a “1 to 10” range is intended to include all sub-ranges between (and including) the minimum recited value of 1 and the maximum recited value of 10, that is, having a minimum value equal to or greater than that 1 and a maximum value equal to or less than 10. Any maximum numerical limitation recited here is intended to include all the lower numerical limitations implied here and any minimum numerical limitation recited here is intended to include all upper numerical limitations implied here. Thus, Depositors reserve the right to change this disclosure, including the claims, to expressly recite any sub-range implied within the ranges expressly recited here. All such tracks are intended to be inherently disclosed herein in such a way that a change to expressly recite any of such sub-tracks would comply with the requirements of 35 U.S.C. § 112, first paragraph, and 35 U.S.C. §132 (a).
    Grammatical articles "one", "one", "a" and "o", as used herein, are intended to include "at least one" or "one or more", unless otherwise specified. Thus, articles are used here to refer to one or more of one (that is, at least one) of the grammatical objects of the article. As an example, “a component” means one or more components and, therefore, possibly more than one component is included and can be used or employed in an implementation of the described modalities.
    Any patent, publication or other disclosure material is considered to be incorporated, in whole or in part, by reference here it is incorporated here only insofar as the incorporated material does not conflict with existing definitions, statements or other disclosure material established in this disclosure. As such, and to the extent necessary, the disclosure as set forth herein cancels any conflicting material incorporated herein by reference. Any material, or portion thereof, that is considered to be incorporated herein by reference, but which conflicts with existing definitions, statements, or any other disclosure material set forth herein is incorporated only to the extent that there is no conflict between that material and the existing disclosure material.
    The present description includes descriptions of various modalities. It is to be understood that all the modalities described here are illustrative and not limiting examples. Thus, the invention is not limited by the description of the various exemplary, illustrative and non-limiting modalities. Instead, the invention is defined only by claims which can be altered to recite any feature expressly or inherently described or otherwise explicitly or inherently supported by the present disclosure.
    Aspects of this disclosure include non-limiting modalities of actions and articles of steel of double hardness, or "dual hardness". Possible shapes of steel articles in accordance with the present disclosure include, for example, double-strength steel armor plates or other shapes comprising air-curable steel alloys.
    As used herein, an “air-curable” steel alloy refers to a steel alloy that does not require quenching in a liquid to achieve its high final hardness. On the contrary, high hardness can be obtained in an air-hardened steel alloy by cooling from high temperature in the air only. As air-hardenable steel alloys do not need to be quenched in liquid to achieve high hardness, air-hardened steel items such as, for example, air-hardenable steel plates, are not subject to distortion and excessive warping that can occur through quick quenching. The air-curable steel alloys in accordance with the present disclosure can be processed using conventional bonding techniques and then air-cooled to form a double-strength steel armor plate or other article without the need heat treatment after bonding by conventional lamination and liquid quenching to achieve high hardness.
    Armor steel alloys can generally be classified according to the hardness between the following groups: (i) Laminated Homogeneous Armor (“RHA”) alloys have a hardness in the BHN (Brinell Hardness Number) range according to the Military Specification United States of America MIL-A-12560H, and are also referred to as 400 BHN steel armor alloys, (ii) High Hardness Armor (“HHA”) alloys exhibit hardness in the range of 477534 BHN according to the Specification United States Military MIL-DTL-46100E, and are also referred to as 500 BHN steel armor alloys, and (iii) Ultra High Hardness (“UHH”) armor alloys have a minimum hardness of 570 BHN according to the Military Specification of the United States of America MIL-DTL-32332, and are also referred to as 600 BHN steel armor alloys. In addition, air-curable 700 BHN steel armor alloys are under development. In accordance with certain non-limiting modalities, air-hardenable steel reinforcement alloys made by methods herein that are used to form double hardness steel reinforcement include, but are not limited to, alloys selected from RHA alloys, HHA alloys, UHH alloys and potentially 700 BHN steel armor alloys. Currently, the present inventors are not aware of any commercial examples of air-curable 400 BHN and 700 BHN steel reinforcements.
    Figure 1 A is a schematic perspective view and Figure 1 B is a schematic cross-sectional view of a non-limiting embodiment of a double hardness steel article 10 in accordance with the present disclosure. The double hardness steel article 10 can be used as a double hardness reinforcement. The double hardness steel article 10 comprises a layer of a first air-hardenable steel armor alloy 12 having a first alloy hardness and a layer of a second air-hardenable steel alloy layer 14 having a second alloy hardness . In a non-limiting embodiment, the first alloy hardness is greater than the second alloy hardness. A metallurgical connection region 16 fixes at least one region of the first air-curable steel armature alloy 12 and at least one region of the second air-curable steel armature alloy 14. As used herein, a "metallurgical connection" refers to diffusion, welding, ligation, or intermolecular or intergranular attraction between alloys in an interfacial region. In the metallurgical connection region 16, the first air-curable steel armature alloy is inter-fused with the second air-curable steel armature alloy, thereby fixing the two alloys together. Those with current knowledge will understand the nature and techniques that can be used to form a metallurgical bonding region between two steel alloys in order to fix the two steel alloys together. In a non-limiting mode, the metallurgical bonding region has a thickness in the range of about 750 pm to about 1500 pm. It will be understood, however, that a metallurgical connection region of any suitable thickness can be formed to fix together the first air-curable steel armature alloy 12 and the second air-curable steel alloy 14.
    In certain non-limiting embodiments, according to the present disclosure, the first air-curable steel armor alloy has a hardness of at least 574 BHN. A non-limiting example of an air-curable UHH steel armor alloy, or 600 BHN steel armor alloy, having a hardness of at least 574 BHN when air-hardened is the ATI 600-MIL® Ultra High Hard Specialty Steel Armor which is available from ATI Defense, Washington, PA, USA and which is described in pending US Application 573, which is incorporated herein by reference in its entirety. The ATI 600-MIL® Ultra High Hard Specialty Steel Armor comprises, in percentage by weight, 0.42 to 0.52 carbon, 3.75 to 4.25 nickel, 1.00 to 1.50 chromium, 0 , 22 to 0.37 molybdenum, 0.20 to 1.00 manganese, 0.20 to 0.50 silicon, up to 0.020 phosphorus, up to 0.005 sulfur, iron balance and incidental impurities. In a non-limiting embodiment, impurities consist of residual elements as per the requirements of U.S. Military Specification MIL-DTL -32332.
    In certain non-limiting modalities, according to the present disclosure, the second air-curable steel armor alloy has a hardness in the range of 477 BHN to 534 BHN, inclusive. A non-limiting example of an air-curable steel alloy armor having a hardness in the range of 477 BHN to 534 BHN, inclusive, is ATI 500-MIL® High Hard Specialty Steel Armor which is also available from ATI Defense. ATI 500-MIL® High Hard Specialty Steel Armor comprises, by weight, 0.22 to 0.32 carbon, 3.50 to 4.00 nickel, 1.60 to 2.00 chromium, 0, 22 to 0.37 molybdenum, 0.80 to 1.20 manganese, 0.25 to 0.45 silicon, up to 0.020 phosphorus, up to 0.005 sulfur, iron balance and incidental impurities. In a non-limiting embodiment, impurities consist of residual elements as per the requirements of U.S. Military Specification MIL-DTL46100E. In certain non-limiting embodiments according to the present disclosure, the first air-curable steel armor alloy has a hardness of at least 574 BHN and the second air-curable steel armor alloy has a hardness in the range of 477 BHN a 534 BHN, inclusive.
    Again with reference to Figures 1A and 1B, the double hardness steel article 10 can be in the form of, for example, a double hardness steel armature plate manufactured from air-curable steel alloys having different values of hardness. The front side 18 of the double-hardened steel armature article or armature 10 includes the first air-curable steel armature alloy 12 which has a relatively high hardness value. The front side 18 includes an “impact face” which is an exposed face of the first air-hardenable steel armor alloy 12. A ballistic projectile breaks and / or flattens in contact with the front side 18. The rear side 19, or backing plate of the double hardness air-curable steel armature plate 10 comprises the second steel armature alloy 14 which has lower hardness than the first air-curable steel armature alloy 12. The side softer and more ductile posterior 19 serves to capture fragments of the projectile passing through the front side 18 and absorbs energy from an impact projectile after the projectile impacts the impact face. While not wishing to stick to any particular theory of operation, it is believed that the presence of the back side 19 and the metallurgical bond between the first and the second air-hardenable steel armor alloys 12, 14 inhibits cracking and / or propagation of cracks on the relatively hard front side 18 when impacted by a ballistic projectile.
    In a non-limiting embodiment, the first air-curable steel armature alloy 12 on the front side 18 of the double-hardened steel article or armature 10 has a Rockwell C hardness of 58 to 65 Rc. In another non-limiting embodiment, the second air-hardenable steel armature alloy 14 comprising the rear side 19 or back plate of the double-hardened steel article or armature 10 has a Rockwell C hardness of 45 to 55 Rc. In yet another embodiment, the difference between the Rockwell C hardness of the first air-curable steel armor alloy 12 and the second air-curable steel armor alloy 14 is about 10 to 15 Rc points.
    In another non-limiting embodiment, the first air-curable steel armor alloy 12 on the front side 18 of the double hardness steel article 10 may conform to U.S. Military Specification MIL-DTL-32332 (MR). In another non-limiting embodiment, the second air-hardenable steel armor alloy 14 comprising the back side 19 or back plate of the double hardness steel article 10 conforms to U.S. Military Specification MIL-DTL-46100E (MR).
    It is within the scope of the present disclosure to metallurgically bind any suitable combination of different air-curable steel armor alloys that are known now or hereafter by a person of ordinary skill in the art, to provide a steel article of double hardness. For example, in certain non-limiting embodiments, an air-curable 400 BHN steel armature alloy may be metallurgically bonded to an air-curable 500 BHN armature alloy or an air-curable 600 BHN steel armature alloy. In such cases, the harder alloy would serve as the first air-hardenable steel armor alloy and the first side, which would typically be exposed to the ballistic threat, so as to be initially contacted by an incoming ballistic projectile.
    Table 1 lists several non-limiting modalities of double hardness articles according to the present disclosure that can be manufactured by a method including metallurgically joining together combinations of air-hardenable steel reinforcement alloys of different hardnesses. In each of these combinations of air-hardenable steel armor alloys listed in Table 1, with reference to the non-limiting modality of article 10 illustrated in Figures 1A and 1B, for example, the alloy of the particular combination exhibiting greater hardness would serve as the first air-hardenable steel armor alloy 12, included on the front side 18, and the alloy exhibiting less hardness would serve as the second air-hardenable steel armor alloy included on the back side 19. The references in Table 1 to 400, 500, 600 and 700, respectively, are for air-curable 400 BHN steel armature alloys, an air-curable 500 BHN steel armature alloy, an air-curable 600 BHN steel armature alloy and a 700 steel armature alloy Air-curable BHN. In combinations of Table 1 in which similar types of alloys are combined such as the first and the second air-curable steel armature alloys (for example, ""), the first air-curable steel armature alloy, which is included on the first side 18 of the plate 10, it will have greater hardness than the second air-curable steel armor alloy, which is included on the rear side 19.
    With reference to Table 1, certain non-limiting embodiments of a steel plate of double hardness or other steel article of double hardness according to the present disclosure combine the following two types of air-curable alloy as the first steel alloy air-curable and the second air-curable steel alloy, respectively: steel alloy 400 BHN (highest hardness) + steel alloy 400 BHN (lowest hardness); alloy steel 500 BHN + alloy steel 400 BHN, alloy steel 500 BHN (highest hardness) + alloy steel 500 BHN (lowest hardness); alloy steel 600 BHN + alloy steel 400 BHN, alloy steel 600BHN + alloy steel 500 BHN, alloy steel 600BHN (highest hardness) + alloy steel 600 BHN (lowest hardness); alloy steel 700 BHN + alloy steel 400 BHN, alloy steel 700 BHN + alloy steel 500 BHN; 700 BHN steel alloy + 600 BHN steel alloy and 700 BHN steel alloy (highest hardness) + 700 BHN steel alloy (lowest hardness).
    In certain non-limiting embodiments, according to the present disclosure, the second air-curable steel alloy comprises an air-curable self-correcting steel. As used herein, “self-alerting steel” refers to a steel in which the carbon in the steel is partially precipitated from portions of the martensitic phase during cooling in air, forming a fine dispersion of iron carbides in an iron matrix oc, which increases the rigidity of the steel alloy. In certain non-limiting embodiments in accordance with the present disclosure, a self-caking steel included as the second air-curable steel alloy exhibits tensile properties at room temperature including tensile strength of at least 260 Ksi (1,792 MPa), resistance to flow of at least 150 Ksi (1,034 MPa) and elongation of at least 13%. In another non-limiting embodiment according to the present disclosure, a self-prevented steel included as the second air-curable steel alloy exhibits stress properties at room temperature including tensile strength of at least 240 Ksi (1,655 MPa), yield strength at least 140 Ksi (965 MPa) and elongation of at least 9%. In certain non-limiting embodiments, an air-curable self-prevented steel that can be used as the second air-curable steel alloy in dual hardness steel articles according to the present disclosure has the minimum V Charpy notch impact properties listed in Table 2, as measured according to standard test methods listed in ASTM A. The V notch impact notch test is a rapid strain rate impact test, which measures the ability of a steel alloy to absorb energy, thus providing a measure of the hardness of a steel alloy.
    In another non-limiting modality, according to this disclosure, an air-curable self-prevented steel that can be used as the second air-curable steel alloy in double hardness steel articles according to the present disclosure is ATI 500-MIL® High Hard Specialty Steel Armor. In another non-limiting modality, an air-tempered steel that can be included as the second air-hardenable steel alloy in certain dual-hardness steel articles according to the present disclosure is AISI Grade 4820 steel alloy (UNS G48200 ) having nominal composition ranges, in percentages by weight, from 0.18% to 0.23% carbon, 0.70% manganese, up to 0.035% phosphorus, up to 0.04% sulfur, 0 ,, 30% silicon, 3.25 to 3.75% nickel, 0.30% molybdenum, iron and incidental impurities, and having properties as listed in ASTM A29 / A29M 05.
    In certain non-limiting embodiments of a dual hardness steel article according to the present disclosure at least one of the first air-hardenable steel alloy and the second air-hardenable steel alloy comprises a nickel-molybdenum-chromium steel alloy air-curable. In certain non-limiting embodiments of a double hardness steel article according to the present disclosure, the first air-curable steel alloy is a nickelmolybdenum-chromium steel alloy which comprises, consists essentially of, or consists of, in percentage by weight, 0.42 to 0.52 carbon, 3.75 to 4.25 nickel, 1.00 to 1.50 chromium, 0.22 to 0.37 molybdenum, 0.20 to 1.00 manganese, 0.20 to 0.50 silicon, up to 0.020 phosphorus, up to 0.005 sulfur, iron and impurities. In certain other non-limiting embodiments of a dual hardness steel article according to the present disclosure, the first air-curable steel alloy is a nickel-molybdenum-chromium steel alloy which comprises, consists essentially of, or consists of , in percentage by weight, 0.22 to 0.32 carbon, 3.50 to 4.00 nickel, 1.60 to 2.00 chromium, 0.22 to 0.37 molybdenum, 0.80 to 1.20 manganese, 0.25 to 0.45 silicon, up to 0.020 phosphorus, up to 0.005 sulfur, iron and incidental impurities.
    One aspect according to the present disclosure is directed to articles of manufacture comprising or consisting of a double hardness steel alloy article comprising air-curable steel alloys according to the present disclosure. In certain, non-limiting embodiments, the article of manufacture is selected from armor, an explosion-proof vehicle hull, a V-shaped explosion-protection vehicle hull, an lower explosion-protective vehicle hull, and an explosion-proof housing.
    An additional aspect according to the present disclosure is directed to methods of fabricating a double hardness steel article such as, for example, a double hardness steel reinforcement in the form of a plate or other article. With reference to the flowchart of Figure 2, a non-limiting embodiment of a method 20 in accordance with the present disclosure for making a steel reinforcement of double hardness includes the supply (step 21 in Figure 2) of a first piece of hardenable steel alloy to the air comprising a first matching surface and having a first part hardness, and the supply (22) of a second air-curable steel alloy piece comprising a second matching surface and having a second part hardness. In certain non-limiting embodiments of method 20, the hardness of the first part is greater than the hardness of the second part. In various non-limiting embodiments of method 20, each of the first piece of air-curable steel alloy and the second piece of air-curable steel alloy is independently chosen from a plate, a plate, a sheet and a cast of an air-curable steel alloy. Again, referring to Figure 2, the first piece of air-curable steel alloy and the second piece of air-curable steel alloy are positioned (23) so that at least a portion of the first matching surface contacts the least a portion of the second matching surface. In a non-limiting embodiment, the total portion of the first correspondence surface contacts the entire portion of the second correspondence surface. The first piece of air-curable steel alloy is metallurgically attached to the second piece of air-curable steel alloy (24) to form a metallurgically attached assembly. The metallurgically attached assembly is hot rolled (25) to provide a metallurgical bonding region between all or a portion of the first matching surface and the second matching surface, thereby metallurgically bonding together the first piece of hardenable steel alloy to the air and the second piece of air-curable steel alloy. The hot-rolled assembly is cooled (26). In certain non-limiting embodiments, at least a portion of at least one of the first matching surface and the second matching surface is optionally ground before the positioning step (23).
    As noted, in method 20 of Figure 2 the first piece of air-curable steel alloy is metallurgically attached to the second piece of air-curable steel alloy to form a metallurgically fixed assembly before hot rolling. As used herein, "metallurgically fixed" refers to the bonding of alloys by diffusion, bonding, intermolecular or intergranular attraction between alloys or between alloys and a welding alloy. The intermediate article produced by metallurgical fixing of the first and the second air-curable steel alloy parts together is referred to here as a metallurgically fixed assembly or welded assembly for ease of reference. In certain non-limiting embodiments of a method according to the present disclosure, metallurgically attaching the first piece of air-curable steel alloy to the second piece of air-curable steel alloy comprises fixing the first and second parts of curable steel alloys in air together by welding together at least one region of the periphery of the first correspondence surface and at least one region of the periphery of the second correspondence surface. In certain non-limiting embodiments, metallurgically attaching the first piece of air-curable steel alloy to the second piece of air-curing steel alloy comprises welding together the entire periphery of the first correspondence surface and the entire periphery of the second correspondence surface. The metallurgical fastening (24) of the first and second pieces of air-curable steel alloy together properly positions the two pieces so that they can be metallurgically joined together by a subsequent hot rolling step. Given this fact, it is not necessary to weld or otherwise metallurgically fasten the entire periphery of the first correspondence surface and the entire periphery of the second correspondence surface together.
    In another non-limiting embodiment, metallurgically affixing the first air-curable steel alloy piece to the second air-curable steel alloy piece to form a metallurgically fixed assembly comprises explosive connection of at least one region of the first matching surface and at least a region of the second correspondence surface. The explosive bonding process for metals and metal alloys is known to a person with ordinary knowledge in the art and does not need to be elaborated further here.
    In certain non-limiting embodiments of method 20, before metallurgically fixing the first and second pieces of air-curable steel alloy (24), it may be necessary or desirable to prepare the first and second matching surfaces, for example, by grinding the all or a portion of one or both surfaces. In certain non-limiting embodiments of method 20, before hot rolling of the metallurgically fixed assembly it may be desirable to evacuate air between the first and the second matching surface in the metallurgically fixed assembly. These additional steps can better ensure the formation of a suitable metallurgical bond between the first and the second piece of air-curable steel alloy when hot rolling the metallurgically fixed assembly. Those with current knowledge will be able, without undue experimentation, to determine whether these pre-hot rolling steps are necessary or desirable.
    Again referring to Figure 2, method 20 includes hot rolling (25) the metallurgically attached assembly to form a metallurgical bond between at least a portion of the first matching surface of the first piece of air-curable steel alloy and the minus a portion of the second matching surface of the second piece of air-curable steel alloy. In certain non-limiting embodiments of method 20, hot rolling (25) comprises hot rolling the assembly metallurgically fixed at a hot rolling temperature in the range of about 700 ° F (371.1 ° C) to about 2100T (1149 ° C), inclusive. In a non-limiting mode, the minimum temperature of the hot rolled assembly coming from the laminator during the final hot rolling is about 700 ° F (371.1 ° C). In another non-limiting embodiment, hot rolling (25) is carried out with the assembly metallurgically fixed at a hot rolling temperature that is greater than 0.5Tm and is even the highest temperature at which no incipient melting of the first and of the second air-curable steel alloy part occurs, where Tm is the melting temperature of the air-curable steel alloy part having the highest melting temperature in the metallurgically fixed assembly. The hot rolling (25) of the metallurgically fixed assembly is conducted to metallurgically join the first and the second air-curable steel alloy part over all or a portion of its interface, thus providing a steel alloy part double hardness with adequate integrity. Hot rolling produces a metallurgical bonding region in which the first and second air-hardenable steel alloys are interdiffused. Those who have a common skill, by reading this disclosure can determine an appropriate hot rolling temperature without undue experimentation. Furthermore, since the technique of hot rolling a set of alloy steel parts to metallurgically connect the parts together along an interface is known to those of ordinary skill, the hot rolling step according to The methods of the present disclosure can be successfully carried out by ordinarily qualified people, without further discussion here.
    In certain non-limiting embodiments of method 20, the hot rolling of the metallurgically fixed assembly (25) comprises hot rolling the assembly to a thickness suitable for use as a steel plate of double hardness or other article. Non-limiting examples of a possible range of article thicknesses range from, for example, a 0.040 inch (0.102 centimeter) thick sheet to a 3 inch (7.62 cm) thick plate. In other non-limiting modalities of method 20, the hot rolling of the metallurgically fixed assembly comprises hot rolling of the assembly to an intermediate thickness, sandblasting of at least one outer surface of the assembly and hot lamination of the sandblasted assembly. grain of sand to a thickness suitable for use as a steel plate of double hardness or other article. These other items include, for example, items selected from an explosion-protected vehicle hull, a V-shaped protective vehicle hull, an explosion-protected vehicle bottom and an explosion-protected cabinet.
    In certain non-limiting embodiments of method 20, hot rolling of the metallurgically fixed assembly results in a metallurgical bond substantially along the entire interface of the first and second opposing matching surfaces of the first air-curable steel alloy and the second air-curable steel alloy, respectively. In such a case, the resulting double hard steel article may have the structure, for example, of article 10 schematically shown in Figures 1A and 1B, in which the metallurgical connection region 16 is produced in hot rolling and extends along substantially the entire interface between the first air-curable steel alloy 12 and the second air-curable steel alloy 14.
    As the air-curable steel alloys of the hot-rolled assembly cool in air from the hot-rolling temperature, the alloys harden to the desired hardness, without the need for post-laminating bonding steps to achieve high hardness. For example, a 400 BHN steel alloy included as the first or second air-curable steel alloy in the hot rolled assembly will develop BHN hardness in cooling in ambient air from the hot rolling temperature. A 500 BHN steel alloy included as the first or second air-curable steel alloy in the hot rolled assembly will develop BHN hardness in cooling in ambient air from the hot rolling temperature. A 600 BHN steel alloy included as the first or second air-hardenable steel alloy in the hot rolled assembly will develop a minimum hardness of 570 BHN when cooling in ambient air from the hot rolling temperature. As air-hardenable steel armature alloys such as, for example, 400 BHN, 500 BHN, 600 BHN and 700 BHN steel armature alloys, do not require post-laminating bonding steps, such as austenitization, oil quenching, double hard steel alloy articles made according to the methods of the present disclosure can be manufactured up to a size limited only by the hot rolling equipment available, while maintaining the desired ballistic strength properties. Since the conventional post-hot rolling step of oil quenching is not necessary to achieve the desired hardness in air-hardenable alloys as used in the articles and methods of the present disclosure, it may not be necessary to flatten the double hardness steel alloy articles made by the methods as discussed here. Tempered articles in the present disclosure may be unnecessary for certain applications, but may still be necessary for others. Tempering can improve the performance of the article by increasing the stiffness of the article. When flattening is necessary, it will be required to a lesser degree because the distortion by heat treatment, as a result of modalities of the methods of this disclosure, will be less than materials tempered in oil. In addition, because of the air-curable nature of the alloys used in the present methods and articles, mechanically sawing double hard steel alloy articles as disclosed herein does not result in warping of the articles.
    The following examples are intended to further describe certain non-limiting modalities, without restricting the scope of the present invention. Those of ordinary skill in the art will appreciate that variations on the following examples are possible within the scope of the invention which is defined only by the claims. EXAMPLE 1
    In a non-limiting example of a double hardness air-curable steel armature according to the present disclosure, ATI 600-MIL® Ultra High Hard Specialty Steel Armor alloy is used for the front or impact side of the armature and ATI 500 alloy ® High Hard Specialty Steel Armor is used as the back side or support plate of the armature. Ingot surfaces are ground using conventional practices. The continuously fused ingots or slabs of the two alloys are heated to a first temperature of about 1300 ° F (704 ° C), equalized, retained at the first temperature for 6 to 8 hours, heated to about 150 ° F / h (66 ° C / h) to a second temperature of about 2050 ° F (1121 ° C) and retained at the second temperature for about 30 minutes or more per inch of thickness. As an example, the ATI 600-MIL® steel armature alloy ingot is hot rolled up to a 2.80 inch (7.11 cm) plate thickness. The ATI 500-MIL® steel armor alloy ingot is hot rolled up to an over-size of 3.30 inches (8.38 hundred) plate thickness. The plates are stress-relieved at 1250 ° F (676.7 ° C) for a minimum of 12 hours. Patterns on each plate are saw cut to the same width and length for assembly correspondence. Each plate is flattened and laminated to gauge. As an example, the ATI 600-MIL® steel armor plate is laminated to a thickness of 2.50 inches (6.35 cm) and the ATI 500-MIL® steel armor plate is laminated to a thickness of 3 .00 inches (7.62 cm). The surfaces of the rolled ingots are thoroughly cleaned to remove any foreign matter, such as oil and lubricants.
    A chamfer is machined at a peripheral edge of each plate to facilitate welding. Surfaces are sandblasted using conventional procedures. For storage, the plates are covered with paper and stored internally to inhibit oxidation. Plates that are not welded within seven days are reblasted to remove any oxidation. An ATI 600-MIL® steel armature plate is arranged on an ATI 500-MIL® steel armature plate and the plates are welded together at the chamfered edges aligned using low hydrogen welding rod or wire (designation 7018 for welding} to provide a metallurgically fixed assembly of the two plates.
    The welded assembly (metallurgically fixed) is stamped to identify the hard side, that is, the steel armor side ATI 600-MIL® and the assembly is heated to 2200 ° F (1204 ° C) or less and held at temperature for 30 to 45 minutes or more per inch of the set (11.8 to 17.7 minutes or more per cm of set). The assembly is then laminated to a new plate with the ATI 600-MIL® steel armor side as the top side to a thickness in the range of 3.5 inches (8.9 cm) to 5.0 inches ( 12.7 cm).
    The new laminated plate assembly is conventionally sandblasted with the hard side up and then heated to 1750 ° F (954.4 ° C), retained for 30 to 45 minutes per inch of assembly (11.8 to 17.7 minutes per set of cm) and laminated to the finished thickness. The laminated assembly is standardized at 1600 ° C ± 200 ° F (871.1 ° C ± 93 ° C), cooled in the air and flattened if necessary. Flattening may include conventional flattening procedures, or may include applying sufficient tensile or compressive stresses to the laminate assembly to maintain flattening during normalization treatment, as disclosed in US Patent Application 809, which is incorporated herein by reference in its wholeness. Flattening may or may not be necessary in certain non-limiting modalities of methods of making double hardness steels in accordance with the present disclosure. Even if flattening is necessary, in certain modalities of methods described herein, however, it may be necessary to a lesser extent than in conventional methods due to the reduced distortion of heat treatment in modalities of the methods described herein.
    The hot rolled assembly is tempered at temperatures between 175 ° F (79.4 ° C) to 250 ° F (121 ° C) for 30 minutes to 120 minutes. The double hardness air-hardened steel armature thus produced is sandblasted and sandblasted with water or abrasive cut to the desired size.
    This disclosure was written with reference to several exemplary, illustrative and non-limiting modalities. However, it will be recognized by persons of ordinary skill in the art that various substitutions, modifications or combinations of any of the described modalities (or portions thereof) can be made without departing from the scope of the invention, as defined only by the claims. Thus, it is contemplated and understood that the present disclosure includes additional modalities not expressly established herein. Such modalities can be obtained, for example, by combining and / or modifying any of the disclosed steps, ingredients, constituents, components, elements, characteristics, aspects, and the like, of the modalities described herein. Thus, this disclosure is not limited by the description of the various exemplary, illustrative and non-limiting modalities, but only by the claims. Accordingly, it will be understood that the claims may be amended during the course of the present patent application to add resources to the claimed invention as varied herein.
    权利要求:
    Claims (30)
    [0001]
    Double hardness steel article CHARACTERIZED by the fact that it comprises:
    a first piece of preformed air-curable steel alloy having a first alloy hardness;
    a second preformed air-curable steel alloy piece having a second alloy hardness, where the first alloy hardness is greater than the second alloy hardness, and at least one of the first hardenable steel alloy part air and the second piece of air-curable steel alloy comprises a nickel-molybdenum-chromium steel alloy; and
    an intermediate metallurgical bonding region between the first air-curable steel alloy part and the second air-curable steel alloy part, where a thickness of the metallurgical bonding region is in the range of 750 pm to 1500 pm.
    [0002]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that:
    the first piece of air-curable steel alloy has a hardness of at least 574 BHN, and
    the second piece of air-curable steel alloy has a hardness in the range of 477 BHN to 534 BHN inclusive.
    [0003]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that:
    at least one of the first air-curable steel alloy part and the second air-curable steel alloy part is individually selected from the group consisting of a 400 BHN steel alloy, a 500 BHN steel alloy and an alloy 600 BHN steel.
    [0004]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that the second piece of air-curable steel alloy comprises a self-correcting steel alloy.
    [0005]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that the first piece of air-curable steel alloy comprises, in percentage by weight:
    0.42 to 0.52 carbon;
    3.75 to 4.25 nickel;
    1.00 to 1.50 chromium;
    0.22 to 0.37 molybdenum;
    0.20 to 1.00 of manganese,
    0.20 to 0.50 silicon;
    up to 0.020 phosphorus;
    up to 0.005 sulfur; and
    iron and impurities
    [0006]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that the second piece of air-curable steel alloy comprises, in percentage by weight:
    0.22 to 0.32 carbon;
    3.50 to 4.00 of nickel;
    1.60 to 2.00 chromium;
    0.22 to 0.37 molybdenum;
    0.80 to 1.20 of manganese;
    0.25 to 0.45 silicon;
    up to 0.020 phosphorus;
    up to 0.005 sulfur;
    iron, and
    impurities.
    [0007]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that the first piece of air-curable steel alloy essentially consists of, in percentage by weight:
    0.42 to 0.52 carbon;
    3.75 to 4.25 nickel;
    1.00 to 1.50 chromium;
    0.22 to 0.37 molybdenum;
    0.20 to 1.00 of manganese,
    0.20 to 0.50 silicon;
    up to 0.020 phosphorus;
    up to 0.005 sulfur; and
    iron and incidental impurities
    [0008]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that the second piece of air-curable steel alloy essentially consists of, in percentage by weight:
    0.22 to 0.32 carbon;
    3.50 to 4.00 of nickel;
    1.60 to 2.00 chromium;
    0.22 to 0.37 molybdenum;
    0.80 to 1.20 of manganese;
    0.25 to 0.45 silicon;
    up to 0.020 phosphorus;
    up to 0.005 sulfur;
    iron, and
    incidental impurities
    [0009]
    Steel article of double hardness, according to claim 1, CHARACTERIZED by the fact that the article is selected from a steel armor of double hardness, a protective shell of double hardness explosion, a shell of double hardness protective of V-shaped explosion, a lower hardness explosion protection vehicle cup and double hardness explosion protection cabinet.
    [0010]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that the second piece of air-curable steel alloy has a second alloy hardness of 45 to 55 Rc.
    [0011]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that the first air-hardenable steel alloy has a first alloy hardness that is 10 to 15 points Rc greater than the second alloy hardness.
    [0012]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that the first piece of air-curable steel alloy is in accordance with MIL-DTL-32332 (MR) specification.
    [0013]
    Double hardness steel article according to claim 1, CHARACTERIZED by the fact that the second piece of air-curable steel complies with MIL-DTL-46100E (MR) specification.
    [0014]
    Steel armor of double hardness CHARACTERIZED by the fact that it comprises:
    a first piece of preformed air-curable steel alloy having a first alloy hardness of at least 574 BHN and comprising, in percentage by weight,
    0.42 to 0.52 carbon,
    3.75 to 4.25 nickel,
    1.00 to 1.50 chrome,
    0.22 to 0.37 molybdenum
    0.20 to 1.00 of manganese,
    0.20 to 0.50 silicon,
    up to 0.020 phosphorus,
    up to 0.005 sulfur,
    iron, and
    impurities;
    a second piece of preformed air-curable steel alloy having a second alloy hardness in a range of 477 BHN to 534 BHN and comprising, in percentage by weight,
    0.22 to 0.32 carbon,
    3.50 to 4.00 nickel,
    1.60 to 2.00 chrome,
    0.22 to 0.37 molybdenum
    0.80 to 1.20 of manganese,
    0.25 to 0.45 silicon,
    up to 0.020 phosphorus,
    up to 0.005 sulfur,
    iron, and
    impurities, and
    a metallurgical bonding region between the first air-curable steel alloy part and the second air-curable steel alloy part, where a thickness of the metallurgical bonding region is in the range of 750 pm to 1500 pm.
    [0015]
    Method of manufacturing a double hard steel article CHARACTERIZED by the fact that it comprises:
    providing a first piece of air-curable steel alloy comprising a first matching surface and having a first piece hardness;
    providing a second piece of air-curable steel alloy comprising a second matching surface and having a second piece hardness, wherein the first piece hardness is a greater hardness than the second piece hardness;
    arranging the first piece of air-curable steel alloy and the second piece of air-curable steel alloy so that at least a portion of the first matching surface contacts at least a portion of the second matching surface;
    metallurgically attaching the first piece of air-curable steel alloy to the second piece of air-curing steel alloy to form a metallurgically fixed assembly;
    hot laminating the metallurgically attached assembly to form a metallurgical bond between the first matching surface and the second matching surface; and
    cool the hot rolled assembly.
    [0016]
    Method according to claim 15, CHARACTERIZED by the fact that it further comprises grinding at least a portion of at least one of the first matching surface and the second matching surface before disposal.
    [0017]
    Method according to claim 15, CHARACTERIZED in that the metallurgically fastening of the first air-curable steel alloy piece to the second air-curable steel alloy piece to form a metallurgically fixed assembly comprises welding together at least one portion of a periphery of the first correspondence surface and a periphery of the second correspondence surface.
    [0018]
    Method according to claim 15, CHARACTERIZED in that the metallurgically fastening of the first air-curable steel alloy piece to the second air-curable steel alloy piece to form a metallurgically fixed assembly comprises explosive connection of at least one portion of the first correspondence surface and a portion of the second correspondence surface.
    [0019]
    Method according to claim 15, CHARACTERIZED by the fact that the hot rolling of the metallurgically fixed assembly comprises hot rolling of the metallurgically fixed assembly up to a thickness suitable for a steel reinforcement of double hardness.
    [0020]
    Method according to claim 15, CHARACTERIZED by the fact that the hot rolling of the metallurgically fixed assembly comprises hot rolling of the metallurgically fixed assembly to an intermediate size, sandblasting with at least one outer surface of the metallurgically fixed assembly , and hot rolling of the sandblasted assembly to a suitable thickness for a double hardness steel reinforcement.
    [0021]
    Method according to claim 15, CHARACTERIZED by the fact that the hot rolling of the metallurgically fixed assembly comprises hot rolling at a temperature of hot rolling in the range of 2100 ° F (1149 ° C) to 700 ° F (371 , 1 ° C).
    [0022]
    Method according to claim 15, CHARACTERIZED that hot rolling comprises hot rolling at a hot rolling temperature in a temperature range greater than 0.5 times the melting temperature, in degrees Fahrenheit, of the alloy with the highest melting temperature of the first or second piece of steel alloy and even a temperature at which no incipient melting of the first or second piece of steel alloy occurs.
    [0023]
    Method according to claim 15, CHARACTERIZED by the fact that the double hardness steel alloy article comprises:
    a first region of air-curable steel alloy having a hardness of at least 574 BHN;
    a second region of air-curable steel alloy having a hardness in the range of 477 BHN to 534 BHN, inclusive; and
    a metallurgical link between the first air-curable steel alloy region and the second air-curable steel alloy region.
    [0024]
    Method according to claim 15, CHARACTERIZED by the fact that: at least one of the first piece of air-curable steel alloy and the second piece of air-curable steel alloy comprises an alloy individually selected from the group consisting of a alloy steel 400 BHN, alloy steel 500 BHN and alloy steel 600 BHN.
    [0025]
    Method according to claim 15, CHARACTERIZED by the fact that at least one of the first piece of air-curable steel alloy and the second piece of air-curable steel alloy comprises a nickel-steel alloy
    [0026]
    Method according to claim 15, CHARACTERIZED by the fact that the second piece of air-curable steel alloy comprises an alloy of
    [0027]
    Method, according to claim 15, CHARACTERIZED by the fact that the first piece of air-curable steel alloy comprises, in percentage by weight:
    0.42 to 0.52 carbon;
    3.75 to 4.25 nickel;
    1.00 to 1.50 chromium;
    0.22 to 0.37 molybdenum;
    0.20 to 1.00 of manganese,
    0.20 to 0.50 silicon;
    up to 0.020 phosphorus;
    up to 0.005 sulfur;
    iron, and
    impurities.
    [0028]
    Method according to claim 15, CHARACTERIZED by the fact that the second piece of air-curable steel alloy comprises, in percentage by weight:
    0.22 to 0.32 carbon;
    3.50 to 4.00 of nickel;
    1.60 to 2.00 chromium;
    0.22 to 0.37 of Molybdenum;
    0.80 to 1.20 of manganese;
    0.25 to 0.45 silicon;
    up to 0.020 phosphorus;
    up to 0.005 sulfur;
    iron, and
    impurities.
    [0029]
    Method, according to claim 15, CHARACTERIZED by the fact that the first air-curable steel alloy is in accordance with MIL-DTL-32332 (MR) specification.
    [0030]
    Method, according to claim 15, CHARACTERIZED by the fact that the second air-curable steel alloy is in accordance with MIL-DTL-46100E (MR) specification.
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    同族专利:
    公开号 | 公开日
    US10858715B2|2020-12-08|
    DK2661601T3|2016-05-17|
    RU2013136830A|2015-02-20|
    CA2823645C|2019-04-02|
    IL227341A|2016-07-31|
    US10113211B2|2018-10-30|
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    SI2661601T1|2016-07-29|
    AU2011353654B2|2016-01-07|
    TWI512118B|2015-12-11|
    EP2661601B1|2016-03-09|
    MX2013007893A|2013-09-13|
    BR112013017287A2|2016-10-25|
    US20190024204A1|2019-01-24|
    WO2012094160A2|2012-07-12|
    RU2578278C2|2016-03-27|
    HK1188282A1|2014-04-25|
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    KR101945062B1|2019-02-01|
    HUE028888T2|2017-01-30|
    CA2823645A1|2012-07-12|
    JP2014511431A|2014-05-15|
    US9182196B2|2015-11-10|
    US20120174760A1|2012-07-12|
    EP2661601A2|2013-11-13|
    WO2012094160A3|2012-09-07|
    JP5834095B2|2015-12-16|
    ES2571758T3|2016-05-26|
    AU2011353654A1|2013-07-25|
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    法律状态:
    2017-05-23| B25D| Requested change of name of applicant approved|Owner name: ATI PROPERTIES LLC (US) |
    2018-12-18| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-10-01| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-03-31| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2020-06-23| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/12/2011, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    US12/986,213|US9182196B2|2011-01-07|2011-01-07|Dual hardness steel article|
    US12/986.213|2011-01-07|
    PCT/US2011/066691|WO2012094160A2|2011-01-07|2011-12-22|Dual hardness steel article and method of making|
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